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Submissions from 2014

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Fatty Acid Synthesis is Inhibited by Inefficient Utilization of Unusual Fatty Acids for Glycerolipid Assembly, Philip D. Bates, Sean R. Johnson, Xia Cao, Jia Li, Jeong-wan Nam, Jan G. Jaworkski, John B. Ohlrogge, and John Browse

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Di(cyanate Ester) Networks Based on Alternative Fluorinated Bisphenols with Extremely Low Water Uptake, Cynthia A. Corley, Andrew J. Guenthner, Christopher M. Sahagun, Kevin R. Lamison, Josiah T. Reams, Mohammad K. Hassan, Sarah E. Morgan, Scott T. Iacano, and Joseph M. Mabry

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Use of Fluorescent Probes to Determine Molecular Architecture in Phase Separating Epoxy Systems, Kevin B. Davis, Dwaine A. Braasch, Monoj Pramanik, and James W. Rawlins

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Synthesis and Characterization of a Soybean Oil- Based Macromonomer, David Delatte, Ethem Kaya, Laura G. Kolibal, Sharathkumar K. Mendon, James W. Rawlins, and Shelby F. Thames

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Effect of Water and Solvent Selection on the SAFA Purification Times for Metallic Nitride Fullerenes, Steven Stevenson, Coralie B. Rose, Alyssa A. Robson, David T. Heaps, and J. Paige Buchanan

Submissions from 2013

Enantiodivergent Synthesis of Unnatural Alpha-Methyl-Lysine and Proline Analogs from a Common Synthon, Souvik Banerjee, Justin Smith, Jillian Smith, and Douglas Masterson

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Novel Synthesis of Various Orthogonally Protected C-alpha-methyllysine Analogues and Biological Evaluation of a Vapreotide Analogue Containing (S)-alpha-methyllysine, Souvik Banerjee, Walker J. Wiggins, Jessie L. Geoghegan, Catherine T. Anthony, Eugene A. Woltering, and Douglas S. Masterson

Evaluation of Sunscreen Formulation and Effectiveness, LaCrissia J. Bridges, Sandra Greene, and Paige Buchanan

Iodido{4-phenyl-1-[1-(1,3-thiazol-2-yl- N)ethylidene]thiosemicarbazidato-2N ',S}{4-phenyl-1-[1-(1,3-thiazol-2-yl)ethylidene]thiosemicarbazide-S}cadmium(II), Ruddock Cleopatra, Ramaiyer Venkatraman, Wren M. Lisa, and Alvin A. Holder

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Stability Analysis of 4-Species A Beta Aggregation Model: A novel Approach to Obtaining Physically Meaningful Rate Constants, Gaurav Ghag, P. Ghosh, A. Mauro, Vijay Rangachari, and A. Vaidya

Stereodivergent Strategy for the Preparation of Delta-Lactams and Their Use in the Synthesis of a Nipecotic Acid Analog, Daniel A. Hinton, Souvik Banerjee, and Douglas S. Masterson

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Preliminary Anti-Cancer Photodynamic Therapeutic In Vitro Studies With Mixed-Metal Binuclear Ruthenium(II)-Vanadium(IV) Complexes, Alvin A. Holder, Patrick Taylor, Anthony R. Magnusen, Erick T. Moffett, Kyle Meyer, Yiling Hong, Stuart E. Ramsdale, Michelle Gordon, Javelyn Stubbs, Luke A. Seymour, Dhiraj Acharaya, Ralph T. Weber, Paul F. Smith, G. Charles Dismukes, Ping Ji, Laura Menocal, Fengwei Bai, Jennie L. Williams, Donald M. Cropek, and William L. Jarrett

Photocatalytic Hydrogen Production with Mixed-Metal Binuclear Ruthenium(II)-Cobalt(II) Complexes: What a Difference Bridging and Terminal Ligands Can Make, Alvin Holder, Apparao Draksharapu, Jason Olaivar, and Erick Moffett

Synthesis, Crystal Structure of Zn(II) Complex of 2-acetylthiazole N-phenyl-3-thiosemicarbazone, Ruddock Kleopatra, Ramaiyer Venkatraman, Samuel S. R. Dasary, and Alvin A. Holder

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Mathematical Modeling of Amyloid Beta Fibril Formation: Equilibria & Stability, Andrew K. Mauro, Preetam Ghosh, Vijayaraghavan Rangachari, and Ashwin Vaidya

Computational Studies of Isomers of C-80, Taylor McKee, J. Paige Buchanan, and David H. Magers

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Sensitive Determination of Triacetone Triperoxide Explosives Using Electrogenerated Chemiluminescence, Suman Parajuli and Wujian Miao

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A Comparison of the Self Assembled Frameworks of Three Cobalt(II) Coordination Compounds Bearing Dipicolinic Acid and Chelidamic Acid Ligands, Varma H. Rambaran, Travis R. Erves, Kristy Grover, Shawna Balof, LaMaryet V. Moody, Stuart E. Ramsdale, Luke A. Seymour, Don VanDerveer, Donald M. Cropek, and Alvin A. Holder

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Self-Replicating Amyloid-Beta Oligomers Open Doors to New Molecular Mechanisms in Alzheimer Disease, Vijayaraghavan Rangachari, Amit Kumar, Lea Paslay, Daniel Lyons, Sarah E. Morgan, and John Correia

Investigation of Co-Solvent Effects on the Selectivities of PLE Isoenzymes with Various Substrates, Maureen E. Smith, Souvik Banerjee, Marlen Schmidt, and Douglas S. Masterson

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Regioselective Hydration of an Alkene and Analysis of the Alcohol Product by Remote Access NMR: A Classroom Demonstration, Maureen E. Smith, Sara L. Johnson, and Douglas S. Masterson

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Interaction of HMG Proteins and H1 with Hybrid PNA-DNA Junctions, Filbert Totsingan and Anthony J. Bell Jr.

Convenient Esterification of the C-Terminal Carboxylic Acids in Oxidized Glutathione and Other Small Peptides, Emily R. Vogel, Will Jackson, and Douglas S. Masterson

Fluorescent and Electrogenerated Chemiluminescent Studies of Energy Transfer Between CdSe/ZnS and CdTe/CdS Quantum Dots in Aqueous Media, Yiliyasi Wusimanjiang and Wujian Miao

Submissions from 2012

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A Stereoselective Cyclization Strategy for the Preparation of gamma-Lactams and Their Use in the Synthesis of alpha-Methyl-beta-Proline, Souvik Banerjee, Justin Smith, Jillian Smith, Caleb Faulkner, and Douglas S. Masterson

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Flexible Aliphatic-Bridged Bisphenol-Based Polybenzoxazines, Austin D. Baranek, Laken L. Kendrick, Jananee Narayanan, Ginger E. Tyson, Steven Wand, and Derek L. Patton

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Anticancer Activity and Biophysical Reactivity of Copper Complexes of 2-(benzo[d][1,3]dioxol-5-ylmethylene)-N-Alkylhydrazinecarbothioamides, Floyd A. Beckford, Jeffrey Thessing, Alyssa Stott, Alvin A. Holder, Oleg G. Poluektov, Liya Li, and Navindra P. Seeram

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Linker-Free, Silica-Bound Olefin-Metathesis Catalysts: Applications in Heterogeneous Catalysis, Jose Cabrera, Robin Padilla, Miriam Bru, Ronald Lindner, Takeharu Kageyama, Kristina Wilckens, Shawna L. Balof, Hans-Jörg Schanz, Richard Dehn, J. Henrique Teles, Stephan Deuerlein, Kevin Müller, Frank Rominger, and Michael Limbach

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Effect of Acid Value on the Esterification Mechanism of Maleinized Soybean Oil with Cotton, Ericka N. J. Ford, James W. Rawlins, Sharathkumar K. Mendon, and Shelby F. Thames

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Development of a Triazole-Cure Resin System for Composites: Evaluation of Alkyne Curatives, Irene E. Gorman, Rodney L. Willer, Lisa K. Kemp, and Robson F. Storey

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Broadband Dielectric Spectroscopic Studies of Molecular Motions in a Nafion (R) Membrane vs. Annealing Time and Temperature, Mohammad K. Hassan, Kenneth A. Mauritz, and Ahmed Abukmail

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Investigation of the Precipitation Behavior of Asphaltenes in the Presence of Naphthenic acids Using Light Scattering and Molecular Modeling Techniques, David T. Heaps, Praveen K. Madasu, David H. Magers, and J. Paige Phillips Buchanan

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Synthesis of Photolabile Transcription Initiators and Preparation of Photocleavable Functional RNA by Transcription, Faqing Huang and Yongliang Shi

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Mechanisms in the Reactions of Arenediazonium Cations with 2-Nitropropanide Anion, Rajive K. Khanna, Yong M. Jiang, and P.R. Singh

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Expandable Temperature-Responsive Polymeric Nanotubes, Shintaro Kiwano and Marek W. Urban

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Specific Soluble Oligomers of Amyloid-beta Peptide Undergo Replication and Form Non-Fibrillar Aggregates in Interfacial Environments, Amit Kumar, Lea C. Paslay, Daniel Lyons, Sarah E. Morgan, John J. Correia, and Vijayaraghavan Rangachari

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Synthesis, Characterisation, and Preliminary In Vitro Studies of Vanadium(IV) Complexes with a Schiff Base and Thiosemicarbazones as Mixed Ligands, Nerissa A. Lewis, Fange Liu, Luke Seymour, Anthony Magnusen, Travis R. Erves, Jessa Faye Arca, Floyd A. Beckford, Ramaiyer Venkatraman, Antonio González-Sarrías, Frank R. Fronczek, Don G. VanDerveer, Navindra P. Seeram, Aimin Liu, William L. Jarrett, and Alvin A. Holder

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Ultrasensitive Electrogenerated Chemiluminescence Biosensor for the Determination of Mercury Ion Incorporating G4 PAMAM Dendrimer and Hg(II)-Specific Oligonucleotide, Fen Ma, Yu Zhang, Honglan Qi, Qiang Gao, Chengxiao Zhang, and Wujian Miao

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Host-Guest Chemistry of Pyrene-Based Molecular Receptors, Erendra Manandhar and Karl J. Wallace

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N-(4-[2.2]paracyclophanyl)-2 '-Hydroxyacetophenone imine: An Effective Paracyclophane Schiff-Base Ligand for use in Catalytic Asymmetric Cyclopropanation Reactions, Douglas S. Masterson, Caitlyne Shirley, and Daniel T. Glatzhofer

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Broadband Dielectric Spectroscopy Studies of Glassy-State Relaxations in Annealed Poly(2,5-benzimidazole), Amol Nalawade, Mohammad K. Hassan, William A. Jarrett, Kenneth A. Mauritz, and Morton H. Litt

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A Robust and High-Throughput Measurement Platform for Monomer Reactivity Ratios from Surface-Initiated Polymerization, Derek L. Patton, Kirk A. Page, Emily A. Hoff, Michael J. Fasolka, and Kathryn L. Beers

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The Natural Product Betulinic Acid Rapidly Promotes Amyloid-β Fibril Formation at the Expense of Soluble Oligomers, Matthew S. Planchard, Michael A. Samel, Amit Kumar, and Vijayaraghavan Rangachari

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Determination of Epoxy Equivalent Weight of Glycidyl Ether Based Epoxides via Near Infrared Spectroscopy, Monoj Pramanik, Sharathkumar K. Mendon, and James W. Rawlins

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Isolation and Characterization of the Prochlorococcus Carboxysome Reveal the Presence of the Novel Shell Protein CsoS1D, Evan W. Roberts, Fei Cai, Cheryl A. Kerfeld, Gordon C. Cannon, and Sabine Heinhorst

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Investigation of the Cosolvent Effect on Six Isoenzymes of PLE in the Enantioselective Hydrolysis of Selected a,a-Disubstituted Malonate Esters, Maureen E. Smith, Souvik Banerjee, Yongliang Shi, Marlen Schmidt, Uwe T. Bornscheur, and Douglas S. Masterson

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Cyclic Tetravinylsiloxanetetraols as Hybrid Inorganic-Organic Thiol-ene Networks, Bradley J. Sparks, Timothy J. Kuchera, Matthew J. Jungman, Adam D. Richardson, Daniel A. Savin, Sukhendu Hait, Joseph Lichtenhan, Mary F. Striegel, and Derek L. Patton

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Selective Synthesis, Isolation, and Crystallographic Characterization of LaSc2N@I-h-C-80, Steven Stevenson, Coralie B. Rose, Juliya S. Maslenikova, Jimmy R. Villarreal, Mary A. Mackey, Brandon Q. Mercado, Kelly Chen, Marilyn M. Olmstead, and Alan L. Balch

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Guanidine-Containing Methacrylamide (Co)polymers via aRAFT: Toward a Cell-Penetrating Peptide Mimic, Nicolas J. Treat, DeeDee Smith, Chengwen Tang, Joel D. Flores, Brooks A. Abel, Adam W. York, Faqing Huang, and Charles L. McCormick

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Dynamic Materials: The Chemistry of Self-Healing, Marek W. Urban

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A Fluorescent Dipyrrinone Oxime for the Detection of Pesticides and Other Organophosphates, Ian Walton, Marauo Davis, Lynsday Munro, Vincent J. Catalano, Peter J. Cragg, Michael T. Huggins, and Karl J. Wallace

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Polymerization Coupled to Oscillating Reactions: (1) A Mechanistic Investigation of Acrylonitrile Polymerization in the Belousov-Zhabotinsky Reaction in a Batch Reactor, Randy P. Washington, William W. West, Gauri P. Misra, and John A. Pojman

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A Re-Examination of the Reaction of 3,4-Diamino[1,2,5]oxadiazole with Glyoxal, Rodney L. Willer, Robson F. Storey, Christopher G. Campbell, Steven W. Bunte, and Damon Parrish

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Crystal Structures of the "two" 4-Aminofurazan-3-Carboxylic Acids, Rodney L. Willer, Robson F. Storey, Mark Frisch, and Jeffery R. Deschamps

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Effect of Structure on Cationic Initiation Efficiency of a Carbocatonic/ATRP Dual Initiator, Yaling Zhu and Robson F. Storey

Submissions from 2011

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A Modified Stokes-Einstein Equation for A Beta Aggregation, Srisairam Achuthan, Bong Jae Chung, Preetam Ghosh, Vijayaraghavan Rangachari, and Ashwin Vaidya

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Covalent Attachment of Multilayers on Poly(tetrafluoroethylene) Surfaces, Nattharika Aumsuwan, Sang-Ho Ye, Marek W. Urban, and William R. Wagner

Divergent Approach for Synthesis of Numerous Unnatural a-Methyllysine Analogs from a Common Optically Pure Synthon for SPPS, Souvik Banerjee, Maureen Smith, and Douglas S. Masterson

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Shape Evolution Control of Phase-Separated Colloidal Nanoparticles, Cathrin C. Corten and Marek W. Urban

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Survey on Educational Uses of Molecular Visualization, Paul Craig, Robert C. Bateman, and Lea Michel

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pH-Responsive Ruthenium-Based Olefin Metathesis Catalysts: Controlled Ring-Opening Metathesis Polymerization in Alcoholic and Aqueous Media upon Acid Addition, Miles A. Dunbar, Shawna L. Balof, Adam N. Roberts, Edward J. Valente, and Hans-Jörg Schanz

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Cathodic Stripping Synthesis and Cytotoxity Studies of Glutathione-Capped CdTe Quantum Dots, Cunwang Ge, Yu Zhao, Jie Hui, Tianyi Zhang, Wujian Miao, and Wei Yu

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Self-Healing Inside a Scratch of Oxetane-Substituted Chitosan-Polyuretheane (OXE-CHI-PUR) Networks, Biswajit Ghosh, Kishore V. Chellappan, and Marek W. Urban

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A Ru-vinylvinylidene Complex: Straightforward Synthesis of a Latent Olefin Metathesis Catalyst, David M. Hudson, Edward J. Valente, Jörg Schachner, Michael Limbach, Kevin Müller, and Hans-Jörg Schanz

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Non-Esterified Fatty Acids Generate Distinct Low-Molecular Weight Amyloid-beta (A beta 42) Oligomers along Pathway Different from Fibril Formation, Amit Kumar, Rebekah L. Bullard, Pritesh Patel, Lea C. Paslay, Dipti Singh, Ewa A. Bienkiewicz, Sarah E. Morgan, and Vijayaraghavan Rangachari

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Structural, EPR Superhyperfine, and NMR Hyperfine Properties of the Cu-Octarepeat Binding Site in the Prion Protein, Yan Ling, Rahul L. Khade, and Yong Zhang

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Metallic Nitride Azafullerenes: A Novel Class of Fullerenes with Interesting Electronic Properties, Yan Ling, Steven Stevenson, and Yong Zhang

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A Pyrene-Based Fluorescent Sensor for Zn2+ ions: A Molecular 'Butterfly', Erendra Manandhar, J. Hugh Broome, Jalin Myrick, Whitney Lagrone, Peter J. Cragg, and Karl J. Wallace

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The Shape of the Sc-2(mu(2)-S) Unit Trapped in C-82: Crystallographic, Computational, and Electrochemical Studies of the Isomers, Sc-2(mu(2)-S)@C-s(6)-C-82 and Sc-2(mu(2)-S)@C-3v(8)-C-82, Brandon Q. Mercado, Ning Chen, Antonio Rodríguez-Fortea, Mary A. Mackey, Steven Stevenson, Luis Echegoyen, Josep M. Poblet, Marilyn M. Olmstead, and Alan L. Balch

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Using the Mini-Session Course Format To Train Students in the Practical Aspects of Modern Mass Spectrometry, Dale A. Rosado Jr., Tina S. Masterson, and Douglas S. Masterson

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Poly(perfluoroalkylation) of Metallic Nitride Fullerenes Reveals Addition-Pattern Guidelines: Synthesis and Characterization of a Family of Sc3N@C-80(CF3)(n) (n=2-16) and Their Radical Anions, Natalia B. Shustova, Dmitry V. Peryshkov, Igor V. Kuvychko, Yu-Sheng Chen, Mary A. Mackey, Curtis E. Coumbe, David T. Heaps, Bridget S. Confait, Thomas Heine, J. Paige Phillips, Steven Stevenson, Lothar Dunsch, Alexey A. Popov, Steven H. Strauss, and Olga V. Boltalina

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Kinetic Analysis of the Interaction Between Poly(amidoamine) Dendrimers and Model Lipid Membranes, Venkataswarup Tiriveedhi, Kelly M. Kitchens, Kerrick J. Nevels, Hamidreza Ghandehari, and Peter Butko

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Conformational and Configurational Analysis of an N,N Carbonyl Dipyrrinone-Derived Oximate and Nitrone by NMR and Quantum Chemical Calculations, Ian Walton, Marauo Davis, Liu Yang, Yong Zhang, Destin Tillman, William L. Jarrett, Michael T. Huggins, and Karl J. Wallace

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Synthesis and Development of a Multifunctional Self-Decontaminating Polyurethane Coating, James H. Wynne, Preston A. Fulmer, D. Michelle McCluskey, Nicole M. Mackey, and J. Paige Phillips Buchanan

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HNO Binding in a Heme Protein: Structures, Spectroscopic Properties, and Stabilities, Liu Yang, Yan Ling, and Yong Zhang

Submissions from 2010

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Removing Organic Nitrogen Compounds From Middle Distillate Fuels with a Catalyst Used as a Filtering Media, J.W. Bauserman, G.W. Mushrush, H. Willauer, J.H. Wynne, J. Paige Phillips Buchanan, J.L. Buckley, and F.W. Williams

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RD114 Envelope Proteins Provide an Effective and Versatile Approach to Pseudotype Lentiviral Vectors, Anthony J. Bell, David Fegen, Maureen Ward, and Arthur Bank

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Carboxysomal carbonic anhydrases: Structure and Role in Microbial CO2 Fixation, Gordon C. Cannon, Sabine Heinhorst, and Cheryl A. Kerfeld

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Effects of Metal Compounds with Distinct Physicochemical Properties on Iron Homeostasis and Antibacterial Activity in the Lungs: Chromium and Vanadium, Mitchell D. Cohen, Maureen Sisco, Colleen Prophete, Kotaro Yoshida, Lung-Chi Chen, Judith T. Zelikoff, Jason Smee, Alvin A. Holder, Jacqueline Stormhuerner, Debbie C. Crans, and Andrew J. Ghio

Effect of Naphthenic acids on Particle Aggregation and Sedimentation Behavior of Asphaltene Suspensions, David T. Heaps, J. Paige Phillips Buchanan, and Praveen K. Madasu

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Addressing Microbial Organelles: A Short Peptide Directs Enzymes to the Interior, Sabine Heinhorst and Gordon C. Cannon

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Synthesis of Symmetrical Thiol-Adenosine conjugate and 5 ' thiol-RNA Preparation by Efficient One-Step Transcription, Faqing Huang and Yongliang Shi

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Organization, Structure, and Assembly of alpha-Carboxysomes Determined by Electron Cryotomography of Intact Cells, Cristina V. Iancu, Dylan M. Morris, Zhicheng Dou, Sabine Heinhorst, Gordon C. Cannon, and Grant J. Jensen

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Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization, Jun Kamada, Kaloian Koynov, Cathrin Corten, Azhar Juhari, Jeong Ae Yoon, Marek W. Urban, Anna C. Balasz, and Krzysztof Matyjaszewski

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Synthesis and Characterization of Physical Crosslinking Systems Based on Cyclodextrin Inclusion/Host-Guest Complexation, Ethem Kaya and Lon J. Mathias

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Bacterial Microcompartments, Carolyn A. Kerfeld, Sabine Heinhorst, and Gordon C. Cannon

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Inhibition of A beta 42 Peptide Aggregation by a Binuclear Ruthenium(II)-Platinum(II) Complex: Potential for Multimetal Organometallics as Anti-amyloid Agents, Amit Kumar, LaMaryet Moody, Jason F. Olaivar, Nerissa A. Lewis, Rahul L. Khade, Alvin A. Holder, Yong Zhang, and Vijayaraghavan Rangachari

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Unprecedented Fe(IV) Species in a Diheme Protein MauG: A Quantum Chemical Investigation on the Unusual Mossbauer Spectroscopic Properties, Yan Ling, Victor L. Davidson, and Yong Zhang

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NMR, IR/Raman, and Structural Properties in HNO and RNO (R = Alkyl and Aryl) Metalloporphyrins with Implication for the HNO-Myoglobin Complex, Yan Ling, Christopher Mills, Rebecca Weber, Liu Yang, and Yong Zhang

Geometric and Electronic Properties of the Largest Metallic Nitride Cluster in Azafullerenes, Yan Ling and Yong Zhang

M(A)Over-Tildessbauer, NMR, Geometric, and Electronic Properties in S=3/2 Iron Porphyrins, Yan Ling and Yong Zhang

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Glass (Tg) and Stimuli-Responsive (Tsr) Transitions in Random Copolymers, Fang Liu, William L. Jarrett, and Marek W. Urban

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Colloidal Films That Mimic Cilia, Fang Liu, Dhanya Ramachandran, and Marek W. Urban

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Recent Advances and Challenges in Designing Stimuli-Responsive Polymers, Fang Liu and Marek W. Urban

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An Improved Method for the Preparation of Protected (R)-2-Methylcysteine: Solution-Phase Synthesis of a Glutathione Analogue, Douglas S. Masterson, Brant L. Kedrowski, and Amanda Blair

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The Carboxysome Shell is Permeable to Protons, Balaraj B. Menon, Sabine Heinhorst, Jessup M. Shively, and Gordon C. Cannon

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A Seven Atom Cluster in a Carbon Cage, the Crystallographically Determined Structure of Sc-4(mu(3)-O)(3)@I-h-C-80, Brandon Q. Mercado, Marilyn M. Olmstead, Christine M. Beavers, Michael L. Easterling, Steven Stevenson, Mary A. Mackey, Curtis E. Coumbe, Joshua D. Phillips, J. Paige Phillips, Josef M. Poblet, and Alan L. Balch

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Sc-2(mu(2)-O) Trapped in a Fullerene Cage: The Isolation and Structural Characterization of Sc-2(mu(2)-O)@C-s(6)-C-82 and the Relevance of the Thermal and Entropic Effects in Fullerene Isomer Selection, Brandon Q. Mercado, Melissa A. Stuart, Mary A. Mackey, Jane E. Pickens, Bridget S. Confait, Steven Stevenson, MIchael L. Easterling, Ramón Valencia, Antonio Rodríguez-Fortea, Josep M. Poblet, Marilyn M. Olmstead, and Alan L. Balch

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Acorn-Shape Polymeric Nano-Colloids: Synthesis and Self-Assembled Films, Anuradha Misra and Marek W. Urban

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Synthesis and Polymerization of New Multifunctional Pyrrolidinone methacrylate Monomers, Jean-Francois Morizur, Hui Zhou, Charles E. Hoyle, and Lon J. Mathias