Diffusion in Random Pores
Physics and Astronomy
We recently reported the results of molecular dynamics simulations for a binary liquid mixture in porous glass. The results for the concentration-fluctuation autocorrelation function showed that the mutual diffusion and the self-diffusion are different. Unfortunately, the linear size of the three-dimensional system used for this simulation was rather small. We carry out the same simulations here using a relatively large two-dimensional system. The results are the same as those for the small three-dimensional system. The self-diffusion departs from the q(2) Fick's pattern while the mutual diffusion follows it more closely. (C) 1999 American Institute of Physics. [S0021-9606(99)50417-0].
Journal of Chemical Physics
(1999). Diffusion in Random Pores. Journal of Chemical Physics, 110(17), 8742-8747.
Available at: http://aquila.usm.edu/fac_pubs/4606