Facile Synthesis and Polymerization of Ether-Substituted Methacrylates
Polymers and High Performance Materials
New difunctional methacrylate monomers containing beta heteroatoms have been synthesized from alpha-hydroxymethylacrylate esters or alpha-chloromethylacryloyl chloride. These monomers are more reactive than their alkane counterparts (e.g., ethacrylates), giving polymers with molecular weights comparable to poly(itaconate)s. The simple synthetic approach described allows a wide range of difunctionalized acrylate monomers to be produced. Variations in both ester and ether substituents were explored for ease of synthesis and polymerization.
Thompson, R. D.,
Barclay, T. B.,
Basu, K. R.,
Mathias, L. J.
(1995). Facile Synthesis and Polymerization of Ether-Substituted Methacrylates. Polymer Journal, 27(4), 325-338.
Available at: http://aquila.usm.edu/fac_pubs/5852