Selectivities in Biomimetic Atom Abstraction Reactions
Document Type
Article
Publication Date
7-29-1991
Department
Chemistry and Biochemistry
School
Mathematics and Natural Sciences
Abstract
Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substituted toluenes decrease in the order Cr = O > Fe = O > Mn = O, which is in accord with the force constants of the M = O bonds in these model oxygenases.
Publication Title
Tetrahedron Letters
Volume
32
Issue
31
First Page
3759
Last Page
3762
Recommended Citation
Khanna, R. K.,
Pauling, T. M.,
Vajpayee, D.
(1991). Selectivities in Biomimetic Atom Abstraction Reactions. Tetrahedron Letters, 32(31), 3759-3762.
Available at: https://aquila.usm.edu/fac_pubs/7045