Title

Pyramidalization of Gd3N Inside a C-80 Cage. The Synthesis and Structure of Gd3N@C-80

Document Type

Article

Publication Date

1-1-2004

Department

Chemistry and Biochemistry

Abstract

The X-ray crystal structure of Gd3N@ C-80.Ni-II( OEP).1.5(benzene) shows that the Gd3N unit within the I-h C-80 cage is pyramidal, whereas Sc3N@ C-80, Sc3N@ C-78, Sc3N@ C-68, Lu3N@ C-80 and Sc2ErN@ C-80 have planar M3N units.

Publication Title

Chemical Communications

Issue

24

First Page

2814

Last Page

2815