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Submissions from 2011

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In Situ Grown Titania Composition for Optimal Performance and Durability of Nafion® Fuel Cell Membranes, Yatin Patil, Sunil Kulkarni, and Kenneth A. Mauritz

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Reduced Crystallinity and Mobility of Nylon-6 Confined Near the Organic-Inorganic Interface in a Phosphate Glass-Rich Nanocomposite Detected by 1H—13C NMR, Aditya Rawal, Xueqian Kong, Yan Meng, Joshua U. Otaigbe, and Klaus Schmidt-Rohr

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Peptide-Based Lipid Mimetics With Tunable Core Properties via Thiol-Alkyne Chemistry, Jacob G. Ray, Jack T. Ly, and Daniel A. Savin

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Alternating Copolymer of Pyridine and 1,4-Diphenyl-1,2,4,5-Tetrazine from Bis-1,3-Dipolar Cycloaddition Polymerization, Abdelwahed R. Sayed and Jeffrey S. Wiggins

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Thiolene-Based Microfluidic Flow Cells for Surface Plasmon Resonance Imaging, Gareth Sheppard, Takao Oseki, Akira Baba, Derek L. Patton, Futao Kaneko, Leidong Mao, and Jason Locklin

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RAFT-Synthesized Copolymers and Conjugates Designed for Therapeutic Delivery of iRNA, DeeDee Smith, Andrew C. Holley, and Charles L. McCormick

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Synthesis of Thiol-clickable and Block Copolypeptide Brushes Via Nickel-Mediated Surface Initiated Polymerization of Alpha-Amino Acid N-carboxyanhydrides (NCAs), Bradley J. Sparks, Jacob G. Ray, Daniel A. Savin, Christopher M. Stafford, and Derek L. Patton

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Synthesis of exo-Olefin Terminated Polyisobutylene by Sulfide/Base Quenching of Living Polyisobutylene, Subramanyam Ummadisetty, David L. Morgan, and Robson F. Storey

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Reversible Imine Shell Cross-Linked Micelles from Aqueous RAFT-Synthesized Thermoresponsive Triblock Copolymers as Potential Nanocarriers for "pH-Triggered" Drug Release, Xuewei Xu, Joel D. Flores, and Charles L. McCormick

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A Comparative Study on the Mechanical and Barrier Characteristics of Polyimide Nanocomposite Films Filled with Nanoparticles of Planar and Tubular Morphology, Vladimir E. Yudin, Joshua U. Otaigbe, Sergei I. Nazarenko, W.D. Kim, and E.N. Korytkova

Submissions from 2010

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Primary Amine-Functionalized Silicon Surfaces via Click Chemistry with α-Alkynyl-Functionalized Poly(2-aminoethyl methacrylate), Alp H. Alidedeoglu, Christopher A. Harris, Nemesio Martinez-Castro, Adam W. York, Charles L. McCormick, and Sarah E. Morgan

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Bioconjugation of D-Glucuronic Acid Sodium Salt to Well-Defined Primary Amine-Containing Homopolymers and Block Copolymers, Alp H. Alidedeoglu, Adam W. York, Dale A. Rosado Jr., Charles L. McCormick, and Sarah E. Morgan

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Nucleophile-Initiated Thiol-Michael Reactions: Effect of Organocatalyst, Thiol, and Ene, Justin W. Chan, Charles E. Hoyle, Andrew B. Lowe, and Mark Bowman

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Synthesis, Thiol-Yne "Click" Photopolymerization, and Physical Properties of Networks Derived from Novel Multifunctional Alkynes, Justin W. Chan, Junghwan Shin, Charles E. Hoyle, Christopher N. Bowman, and Andrew B. Lowe

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Direct RAFT Polymerization of an Unprotected Isocyanate-Containing Monomer and Subsequent Structopendant Functionalization Using "Click"-Type Reactions, Joel D. Flores, Junghwan Shin, Charles E. Hoyle, and Charles L. McCormick

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X-ray Diffraction of Cotton Treated with Neutralized Vegetable Oil-based Macromolecular Crosslinkers, Ericka N.J. Ford, Sharathkumar K. Mendon, Shelby F. Thames, and James W. Rawlins

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Biocompatibility of Synthetic Poly(Ester urethane)/Polyhedral Oligomeric Silsesquioxane Matrices with Embryonic Stem Cell Proliferation and Differentiation, Yan-Lin Guo, Wenshou Wang, and Joshua U. Otaigbe

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Broadband Dielectric Spectroscopic Studies of Nafion®/Silicate Membranes, Mohammad K. Hassan and Kenneth A. Mauritz

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Uniaxial Compression Analysis of Glassy Polymer Networks Using Digital Image Correlation, Stephen R. Heinz and Jeffrey S. Wiggins

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Thiol-Ene Click Chemistry, Charles E. Hoyle and Christopher N. Bowman

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Thiol-Click Chemistry: A Multifaceted Toolbox for Small Molecule and Polymer Synthesis, Charles E. Hoyle, Andrew B. Lowe, and Christopher N. Bowman

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Effects of Chain Conformation On Miscibility, Morphology, and Mechanical Properties of Solution Blended Substituted Polyphenylene and Polyphenylsulfone, Paul J. Jones, Lea C. Paslay, and Sarah E. Morgan

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Chlorinated Polyethylene Nanocomposites: Thermal and Mechanical Behavior, Sritama Kar, Pradip K. Maji, and Anil K. Bhowmick

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Reversible Interpolyelectrolyte Shell Cross-Linked Micelles from pH/Salt-Responsive Diblock Copolymers Synthesized via RAFT in Aqueous Solution, Matthew G. Kellum, Adam E. Smith, Stacey E. Kirkland-York, and Charles L. McCormick

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Tailored Design of Au Nanoparticle-siRNA Carriers Utilizing Reversible Addition-Fragmentation Chain Transfer Polymers, Stacy Kirkland-York, Yilin Zhang, Adam E. Smith, Adam W. York, Faqing Huang, and Charles L. McCormick

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Recent Advances in Graphene Based Polymer Composites, Tapas Kuilla, Sambhu Bhadra, Dahu Yao, Nam Hoon Kim, Saswata Bose, and Joong Hee Lee

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Free Volume, Transport, and Physical Properties of n-Alkyl Derivatized Thiol-Ene Networks: Chain Length Effect, Luke Kwisnek, Mukul Kaushik, Charles E. Hoyle, and Sergei I. Nazarenko

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In Vitro Drug Release Study of Methacrylate Polymer Blend System: Effect of Polymer Blend Composition, Drug Loading and Solubilizing Surfactants on Drug Release, Jun Li, David Barrow, Holly Howell, and Sid Kalachandra

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A Review of Recent Advances in the Polymeric Delivery of Attributes in Cosmetics and Personal Care Products, Robert Y. Lochhead

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Thiol-yne Click Chemistry: A Powerful and Versatile Methodology for Materials Synthesis, Andrew B. Lowe, Charles E. Hoyle, and Christopher N. Bowman

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Facile Polyisobutylene Functionalization via Thiol-ene Click Chemistry, Andrew J.D. Magenau, Justin W. Chan, Charles E. Hoyle, and Robson F. Storey

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Thiol-Terminated Polyisobutylene: Synthesis, Characterization, and Derivatization, Andrew J.D. Magenau, Todd R. Hartlage, and Robson F. Storey

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Functional Polyisobutylenes via a Click Chemistry Approach, Nemesio Martinez-Castro, Andrew J.D. Magenau, and Robson F. Storey

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Non-Extractable Photoinitiators Based On Thiol-Functionalized Benzophenones and Thioxanthones, Hironori Matsushima, Sukhendu Hait, Qin Li, Hui Zhou, Masamitsu Shirai, and Charles E. Hoyle

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Thiol-Isocyanate-Acrylate Ternary Networks by Selective Thiol-Click Chemistry, Hironori Matsushima, Junghwan Shin, Christopher N. Bowman, and Charles E. Hoyle

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The Novel Photocurable Network: Urea-tetraacrylate/thiol System, Hironori Matsushima, Junghwan Shin, Justin W. Chan, Masamitsu Shirai, and Charles E. Hoyle

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Nonwetting, Nonrolling, Stain Resistant Polyhedral Oligomeric Silsesquioxane Coated Textiles, Rahul Misra, Robert D. Cook, and Sarah E. Morgan

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Seawater Degradable Thermoplastic Polyurethanes, Scott J. Moravek, Mohammad K. Hassan, David J. Drake, Tim R. Cooper, Jeffrey S. Wiggins, Kenneth A. Mauritz, and Robson F. Storey

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End-Quenching of TiCl4-Catalyzed Quasiliving Polyisobutylene with Alkoxybenzenes for Direct Chain End Functionalization, David L. Morgan, Nemesio Martinez-Castro, and Robson F. Storey

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Primary Hydroxy-Terminated Polylsobutylene via End-Quenching with a Protected N-(omega-Hydroxyalkyl)pyrrole, David L. Morgan and Robson F. Storey

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Polymeric Delivery of Therapeutics: Preface, Sarah E. Morgan and Robert Y. Lochhead

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Electrically Stimulated Gradients in Water and Counterion Concentrations Within Electroactive Polymer Actuators, Jong Keun Park, Paul J. Jones, Christopher M. Sahagun, Kirt A. Page, Daniel S. Hussey, David L. Jacobson, and Sarah E. Morgan

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Carbonation of Mg Powder to Enhance the Corrosion Resistance of Mg-Rich Primers, Shashi S. Pathak, Michael D. Blanton, Sharathkumar K. Mendon, and James W. Rawlins

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Investigation on Dual Corrosion Performance of Magnesium-Rich Primer for Aluminum Alloys Under Salt Spray Test (ASTM B117) and Natural Exposure, Shashi S. Pathak, Michael D. Blanton, Sharathkumar K. Mendon, and James W. Rawlins

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Deterioration of Mechanical Properties: A Cause for Fuel Cell Membrane Failure, Yatin Patil, William L. Jarrett, and Kenneth A. Mauritz

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Thiol-Isocyanate-Ene Ternary Networks by Sequential and Simultaneous Thiol Click Reactions, Junghwan Shin, Hironori Matsushima, Christopher Comer, Christopher N. Bowman, and Charles E. Hoyle

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Schizophrenic Self-Assembly of Block Copolymers Synthesized via Aqueous RAFT Polymerization: From Micelles to Vesicles, Adam E. Smith, Xuewei Xu, Stacey E. Kirkland-York, Daniel A. Savin, and Charles L. McCormick

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Stimuli-responsive Amphiphilic (Co)polymers via RAFT Polymerization, Adam E. Smith, Xuewei Xu, and Charles L. McCormick

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Reversible Gold "Locked" Synthetic Vesicles Derived From Stimuli-Responsive Diblock Copolymers, Adam E. Smith, Xuewei Xu, Daniel A. Savin, and Charles L. McCormick

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Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization in an Inverse Microemulsion: Partitioning of Chain Transfer Agent (CTA) and Its Effects on Polymer Molecular Weight, Atsushi Sogabe, Joel D. Flores, and Charles L. McCormick

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Ambient Cure PUSS-Epoxy Matrices for Marine Composites, Samuel J. Tucker, Bruce Fu, Sritama Kar, Stephen R. Heinz, and Jeffrey S. Wiggins

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Synthesis, Characterization and Degradation of Biodegradable Thermoplastic Elastomers from Poly(ester urethane)s and Renewable Soy Protein Isolate Biopolymer, Wenshou Wang, Yan-Lin Guo, and Joshua U. Otaigbe

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Phase Morphology Development in a Low Interfacial Tension Immiscible Polyolefin Blend During Die Extrusion and Melt Spinning, Jinhai Yang, James L. White, and Qibo Jiang

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Structure Development in the Melt Spinning of Polypropylene/Ethylene Butene Copolymer Blends and Birefringence Suppression Effect, J. Yang, Q. Jiang, and James L. White

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Newly UV-Curable Polyurethane Coatings Prepared by Multifunctional Thiol- and Ene-Terminated Polyurethane Aqueous Dispersions: Photopolymerization Properties, Zhenglong Yang, Douglas A. Wicks, Junjie Yuan, Hongting Pu, and Yongsheng Liu

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Rational Design of Targeted Cancer Therapeutics through the Multiconjugation of Folate and Cleavable siRNA to RAFT-Synthesized (HPMA-s-APMA) Copolymers, Adam W. York and Charles L. McCormick

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Rational Design of Biopolymers via Aqueous Reversible Addition-Fragmentation Chain Transfer Polymerization, Stacey E. York, Adam W. York, and Charles L. McCormick

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New Dual Initiators To Combine Quasiliving Carbocationic Polymerization and Atom Transfer Radical Polymerization, Yaling Zhu and Robson F. Storey

Submissions from 2009

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Evidence of Ni(0) Complex Diffusion during Grignard Metathesis Polymerization of 2,5-Dibromo-3-hexylthiophene, Brandon C. Achord and James W. Rawlins

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Aqueous RAFT Polymerization of 2-Aminoethyl Methacrylate to Produce Well-Defined, Primary Amine Functional Homo- and Copolymers, Alp H. Alidedeoglu, Adam W. York, Charles L. McCormick, and Sarah E. Morgan

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Thiol-ene UV-curable Coatings Using Vegetable Oil Macromonomers, Micah Black and James W. Rawlins

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Polymer Degradation and Performance: Preface, Matthew C. Celina, Jeffrey S. Wiggins, and Norman C. Billingham

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Sequential Phosphine-Catalyzed, Nucleophilic Thiol-Ene/Radical-Mediated Thiol-Yne Reactions and the Facile Orthogonal Synthesis of Polyfunctional Materials, Justin W. Chan, Charles E. Hoyle, and Andrew B. Lowe

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The Effects of Primary Amine Catalyzed Thio-Acrylate Michael Reaction On the Kinetics, Mechanical and Physical Properties of Thio-Acrylate Networks, Justin W. Chan, Huanyu Wei, Hui Zhou, and Charles E. Hoyle

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The Nucleophilic, Phosphine-Catalyzed Thiol-ene Click Reaction and Convergent Star Synthesis With RAFT-Prepared Homopolymers, Justin W. Chan, Bing Yu, Charles E. Hoyle, and Andrew B. Lowe

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Photopolymerization of Thiol-Alkynes: Polysulfide Networks, Justin W. Chan, Hui Zhou, Charles E. Hoyle, and Andrew B. Lowe

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Photopolymerization of Thiol-Ene Systems Based on Oligomeric Thiols, Tolecia Clark, Luke Kwisnek, Charles E. Hoyle, and Sergei I. Nazarenko

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Novel Antibacterial Polymers, Bekir Dizman, Mohamed O. Elasri, and Lon J. Mathias

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Reversible "Self-Locked" Micelles from a Zwitterion-Containing Triblock Copolymer, Joel D. Flores, Xuewei Xu, Nicolas J. Treat, and Charles L. McCormick

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Clicking Polymer Brushes with Thiol-yne Chemistry: Indoors and Out, Ryan M. Hensarling, Vanessa A. Doughty, Justin W. Chan, and Derek L. Patton

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Amphiphilic Block Copolymers Synthesized via RAFT: Stimulus-Induced Nanoscale Assembly and Cross-Linking In Aqueous Media, Matthew G. Kellum, Adam E. Smith, Xuewei Xu, and Charles L. McCormick

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Temperature-Induced Ordering and Gelation of Star Micelles Based on ABA Triblocks Synthesized Via Aqueous RAFT Polymerization, Stacey Kirkland-York, Keith Gallow, Jacob Ray, Yueh-lin Loo, and Charles L. McCormick

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Oxygen Transport Properties of Thiol-Ene Networks, Luke Kwisnek, Sergei I. Nazarenko, and Charles E. Hoyle

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(Meth)Acrylate Vinyl Ester Hybrid Polymerizations, Tai Yeon Lee, Neil B. Cramer, Charles E. Hoyle, Jeffrey W. Stansbury, and Christopher N. Bowman

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The Thiol-Isocyanate Click Reaction: Facile and Quantitative Access to Omega-End-Functional Poly(N,N-diethylacrylamide) Synthesized by RAFT Radical Polymerization, Haibo Li, Bing Yu, Hironori Matsushima, Charles E. Hoyle, and Andrew B. Lowe

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The Effect of Thiol and Ene Structures on Thiol-ene Networks: Photopolymerization, Physical, Mechanical and Optical Properties, Qin Li, Hui Zhou, and Charles E. Hoyle

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Comparison of Small Molecule and Polymeric Urethanes, Thiourethanes, and Dithiourethanes: Hydrogen Bonding and Thermal, Physical, and Mechanical Properties, Qin Li, Hui Zhou, Douglas A. Wicks, Charles E. Hoyle, David H. Magers, and Harley R. McAlexander

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Cationic Hydroxyethylcellulose: Anionic Surfactant Interactions in the Presence of Salt, Robert Y. Lochhead and Lisa R. Gandolfi

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Recent Advances in Synthesis, Characterization and Rheological Properties of Polyurethanes and POSS/Polyurethane Nanocomposites Dispersions and Films, Samy A. Madbouly and Joshua U. Otaigbe

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Effect of Method of Preparation on the Rheological Behavior of Polyurethane-Polyhedral Oligomeric Silsesquioxanes Nanostructured Hybrid Films, Samy A. Madbouly, Joshua U. Otaigbe, Ajaya K. Nanda, and Douglas A. Wicks

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Polyurethane-Polyhedral Oligomeric Silsesquioxanes Nanostructured Hybrid Dispersions by the Prepolymer Mixing Process, Samy A. Madbouly, Joshua U. Otaigbe, Ajaya K. Nanda, and Douglas A. Wicks

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Site Transformation of Polyisobutylene Chain Ends into Functional RAFT Agents for Block Copolymer Synthesis, Andrew J.D. Magenau, Nemesio Martinez-Castro, and Robson F. Storey

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Polyisobutylene RAFT CTA by a Click Chemistry Site Transformation Approach: Synthesis of Poly(isobutylene-b-N-isopropylacrylamide), Andrew J. Magenau, Nemesio Martinez-Castro, Daniel A. Savin, and Robson F. Storey

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Primary Halide-Terminated Polyisobutylene: End-Quenching of Quasiliving Carbocationic Polymerization with N-(omega-Haloalkyl)pyrrole, Nemesio Martinez-Castro, David L. Morgan, and Robson F. Storey

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Molecular Miscibility and Chain Dynamics in POSS/Polystyrene Blends: Control of POSS Preferential Dispersion States, Rahul Misra, Alp H. Alidedeoglu, William L. Jarrett, and Sarah E. Morgan

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POSS-Nylon 6 Nanocomposites: Influence of POSS Structure on Surface and Bulk Properties, Rahul Misra, Bruce X. Fu, Andreas Plagge, and Sarah E. Morgan

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Polymerization Kinetics of rac-Lactide Initiated with Alcohol/Stannous Octoate Using In Situ Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy: An Initiator Study, Scott J. Moravek, Jamie M. Messman, and Robson F. Storey

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Copolymers of rac-Lactide and -Caprolactone: Conventional Copolymerization vs. Macroinitiator Copolymerization, Scott J. Moravek and Robson F. Storey

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End-Quenching of Quasi-Living Isobutylene Polymerizations with Alkoxybenzene Compounds, David L. Morgan and Robson F. Storey

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Sulfonium Ion Adducts from Quasiliving Polyisobutylene and Mono-or Disulfides, David L. Morgan and Robson F. Storey

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Poly(Z-lysine)-Based Organogels: Effect of Interfacial Frustration on Gel Strength, Sandeep S. Naik and Daniel A. Savin

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Model Studies of the Durability of a Titania-Modified Nafion Fuel Cell Membrane, Yatin Patil and Kenneth A. Mauritz

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Durability Enhancement of Nafion (R) Fuel Cell Membranes Via In Situ Sol-Gel-Derived Titanium Dioxide Reinforcement, Yatin P. Patil and Kenneth A. Mauritz

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High-Oxygen Barrier Materials Based on Hyperbranced Aliphatic Polyesters, Jason D. Pratt, Brian G. Olson, Justin P. Brandt, Mohammad K. Hassan, Jo Ann Ratto, Jeffrey S. Wiggins, James W. Rawlins, and Sergei Nazarenko

Synthesis of Alkyd/Acrylic Hybrid Latexes For Paper Coating Applications, James W. Rawlins, Richard C. Ferguson, and David E. Delatte

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Synthesis of High Metal-Complexation Linear Elastomers Containing Sym-1,2,4,5-tetrazine Rings, Abdelwahed R. Sayed and Jeffrey S. Wiggins

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Segmented Polythiourethane Elastomers through Sequential Thiol-Ene and Thiol-Isocyanate Reactions, Junghwan Shin, Hironori Matsushima, Justin W. Chan, and Charles E. Hoyle

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Effects of Chemical Modification of Thiol-Ene Networks on Enthalpy Relaxation, Junghwan Shin, Sergei I. Nazarenko, and Charles E. Hoyle

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Physical and Chemical Modifications of Thiol-Ene Networks to Control Activation Energy of Enthalpy Relaxation, Junghwan Shin, Sergei I. Nazarenko, J. Paige Phillips, and Charles E. Hoyle

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Tuning Nanostructure Morphology and Gold Nanoparticle "Locking" of Multi-Responsive Amphiphilic Diblock Copolymers, Adam E. Smith, Xuewei Xu, Thomas U. Abell, Stacey E. Kirkland, Ryan M. Hensarling, and Charles L. McCormick