Synthesis of Substituted 3-Nitroso-2,4-Pyridinediols For Use As Analytical Reagents

Document Type

Article

Publication Date

9-1-1983

Department

Chemistry and Biochemistry

School

Mathematics and Natural Sciences

Abstract

The 5‐bromo, 5‐iodo, and 5‐nitro derivatives of 6‐methyl‐3‐nitroso‐2,4‐pyridinediol were synthesized and shown to produce colored complexes with a number of Group VIII metal ions. Also synthesized were the 1‐pentyl and 1‐octyl esters of 4,6‐dihydroxy‐5‐nitrosopyridine‐3‐carboxylic acid. These compounds showed potential as solvent extraction reagents for certain Group VIII metals.

Publication Title

Journal of Heterocyclic Chemistry

Volume

20

Issue

5

First Page

1363

Last Page

1366

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