Title

Polydopamine‐Graphene Oxide Flame Retardant Nanocoatings Applied via an Aqueous Liquid Crystalline Scaffold

Document Type

Article

Publication Date

7-30-2018

Department

Polymers and High Performance Materials

Abstract

A highly effective flame retardant (FR) nanocoating was developed by conducting oxidative polymerization of dopamine monomer within an aqueous liquid crystalline (LC) graphene oxide (GO) scaffold coating. Due to its high water content, the LC scaffold coating approach facilitated fast transport and polymerization of dopamine precursors into polydopamine (PDA) within the water swollen interlayer galleries. Uniform and periodically stacked (14.5 Å d‐spacing) PDA/GO nanocoatings could be universally applied on different surfaces, including macroporous flexible polyurethane (PU) foam and flat substrates such as silicon wafers. Remarkably, PDA/GO coated PU foam exhibited highly efficient flame retardant performance reflected by a 65% reduction in peak heat release rate at 5 wt% PDA/GO loading in an 80 nm thick coating. While many physically mixed flame retardants are usually detrimental to the mechanical properties of the foam, the PDA/GO coating did not affect mechanical properties substantially. In addition, the PDA/GO coatings were stable in water due to the intrinsic adhesion capability of PDA and the transformation of GO to the more hydrophobic reduced GO form. Given that PDA is produced from dopamine, a molecule prevalent in nature, these findings suggest that significant opportunities exist for new polymeric FRs derived from other natural catechols.

Publication Title

Advanced Functional Materials

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