Title

Selectivities in Biomimetic Atom Abstraction Reactions

Document Type

Article

Publication Date

7-29-1991

Department

Chemistry and Biochemistry

Abstract

Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substituted toluenes decrease in the order Cr = O > Fe = O > Mn = O, which is in accord with the force constants of the M = O bonds in these model oxygenases.

Publication Title

Tetrahedron Letters

Volume

32

Issue

31

First Page

3759

Last Page

3762