Selectivities in Biomimetic Atom Abstraction Reactions
Chemistry and Biochemistry
Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substituted toluenes decrease in the order Cr = O > Fe = O > Mn = O, which is in accord with the force constants of the M = O bonds in these model oxygenases.
Khanna, R. K.,
Pauling, T. M.,
(1991). Selectivities in Biomimetic Atom Abstraction Reactions. Tetrahedron Letters, 32(31), 3759-3762.
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