Ground and Excited State Properties of Some New Highly Water Soluble N-Substituted Thiazine Dyes For Photogalvanic Applications

Document Type

Article

Publication Date

1-1-1983

Department

Chemistry and Biochemistry

School

Mathematics and Natural Sciences

Abstract

Increasing remote cationic charge on the thiazine dye chromophore greatly suppresses ground state aggregation in water, increases the rate constants for intersystem crossing and quenching of the triplet state (T1) by FeII, and the fraction of T1 reduced by FeII, but does not affect the self-quenching of T1 by the ground state.

Publication Title

Journal of the Chemical Society, Chemical Communications

First Page

1521

Last Page

1523

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