Synthesis and Characterization of Polyazothiazole and Polyacetyltetrazine from Novel Bis -Ketohydrazonoyl Dichlorides
Document Type
Article
Publication Date
12-11-2023
School
Polymer Science and Engineering
Abstract
The present work describes the preparation and characterization of new polyazothiazole and polyacetyltrazine polymers in good yields from new bis-(α-ketohydrazonoyl) dichlorides. Synthesis of the new polyazothiazole proceeds through the reaction of bis-(α-ketohydrazonoyl) dichlorides with 1,4-phenylene[bis(carbothioamide)] in a basic medium to afford novel polyazothiazole derivatives. Additionally, the self-polymerization reaction to synthesize polydiacetyltetrazine derivatives based on bis-(α-ketohydrazonoyl) dichlorides is described. The new polyazothiazole and polyacetyltetrazine derivatives were characterized using spectral and thermal techniques.
Publication Title
Polycyclic Aromatic Compounds
First Page
1
Last Page
11
Recommended Citation
Sayed, A. R.,
McNair, O.,
Wiggins, J. S.
(2023). Synthesis and Characterization of Polyazothiazole and Polyacetyltetrazine from Novel Bis -Ketohydrazonoyl Dichlorides. Polycyclic Aromatic Compounds, 1-11.
Available at: https://aquila.usm.edu/fac_pubs/21774