Maximum-Entropy Approach to Classical Hard-Sphere and Hard-Disk Equations of State

Document Type

Article

Publication Date

8-1-1991

Department

Physics and Astronomy

School

Mathematics and Natural Sciences

Abstract

The maximum-entropy procedure for extrapolating series is applied to sum the known virial series for the hard-disk and hard-sphere fluids. This procedure is found to produce numerical results more accurate than Pade approximants, and it agrees with Monte Carlo simulations of these systems. The maximum-entropy results extrapolate the series smoothly to densities arbitrarily near to maximum close packing, and predict no singularities whatsoever.

Publication Title

Journal of Mathematical Physics

Volume

32

Issue

8

First Page

2258

Last Page

2262

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