Mechanisms in the Reactions of Arenediazonium Cations with 2-Nitropropanide Anion

Document Type

Article

Publication Date

9-30-2012

Department

Chemistry and Biochemistry

School

Mathematics and Natural Sciences

Abstract

Lithium 2-nitropropan-2-ide reacts, in MeOH solvent, with benzenediazonium and p-methoxybenzenediazonium cations to give diazo-coupled products, but with p-nitrobenzenediazonium cation by competing electron transfer and diazo-coupling reactions.

Publication Title

Tetrahedron Letters

Volume

32

Issue

40

First Page

5449

Last Page

5452

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