Mechanisms in a Biomimetic Hydroxylation of a Chemical Probe - 5-Nitroacenaphthene
Document Type
Article
Publication Date
12-21-1990
Department
Chemistry and Biochemistry
School
Mathematics and Natural Sciences
Abstract
5-Nitroacenaphthene is hydroxylated by oxometalloporphyrin complexes of chromium, iron, and manganese via hydrogen atom abstraction pathways with charge separation in the transition state dependent on the electrophilicity of the oxygen atom in these model oxygenases.
Publication Title
Journal of Organic Chemistry
Volume
55
Issue
26
First Page
6233
Last Page
6234
Recommended Citation
Khanna, R. K.,
Sutherlin, J. S.,
Lindsey, D.
(1990). Mechanisms in a Biomimetic Hydroxylation of a Chemical Probe - 5-Nitroacenaphthene. Journal of Organic Chemistry, 55(26), 6233-6234.
Available at: https://aquila.usm.edu/fac_pubs/7510