A Study of Hydrogen Microstructure in Amorphous Silicon via Inversion of Nuclear Magnetic Resonance Spectra

Document Type

Article

Publication Date

4-24-2013

Department

Physics and Astronomy

School

Mathematics and Natural Sciences

Abstract

We present an inverse approach for studying hydrogen microstructure in amorphous silicon. The approach consists of generating a prior distribution (of spins/hydrogen) by inverting experimental nuclear magnetic resonance (NMR) data, which is subsequently superimposed on a network of amorphous silicon. The resulting network is then relaxed using a total-energy functional to obtain a stable, low-energy configuration such that the initial spin distribution is minimally perturbed. The efficacy of this approach is demonstrated by generating model configurations that not only have the correct NMR spectra but also satisfy simultaneously experimental structural, electronic and vibrational properties of hydrogenated amorphous silicon.

Publication Title

Journal of Physics: Condensed Matter

Volume

25

Issue

16

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