Synthesis and Purification of a Metallic Nitride Fullerene BisAdduct: Exploring the Reactivity of Gd3N@C80

Document Type

Article

Publication Date

9-21-2005

Department

Chemistry and Biochemistry

School

Mathematics and Natural Sciences

Abstract

This research represents initial functionalization of a Gd3N@C80 metallic nitride fullerene (MNF). Results demonstrate that a bisadduct can be prepared in an isolable yield for this MRI precursor MNF. This Gd3N@C80 bisadduct is synthesized and purified, and preliminary characterization is reported. This is a significant finding as, to date, only MNF monoadducts have been purified.

Publication Title

Journal of the American Chemical Society

Volume

127

Issue

37

First Page

12776

Last Page

12777

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