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Submissions from 2009

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Sequential Phosphine-Catalyzed, Nucleophilic Thiol-Ene/Radical-Mediated Thiol-Yne Reactions and the Facile Orthogonal Synthesis of Polyfunctional Materials, Justin W. Chan, Charles E. Hoyle, and Andrew B. Lowe

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The Effects of Primary Amine Catalyzed Thio-Acrylate Michael Reaction On the Kinetics, Mechanical and Physical Properties of Thio-Acrylate Networks, Justin W. Chan, Huanyu Wei, Hui Zhou, and Charles E. Hoyle

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The Nucleophilic, Phosphine-Catalyzed Thiol-ene Click Reaction and Convergent Star Synthesis With RAFT-Prepared Homopolymers, Justin W. Chan, Bing Yu, Charles E. Hoyle, and Andrew B. Lowe

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Photopolymerization of Thiol-Alkynes: Polysulfide Networks, Justin W. Chan, Hui Zhou, Charles E. Hoyle, and Andrew B. Lowe

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Photopolymerization of Thiol-Ene Systems Based on Oligomeric Thiols, Tolecia Clark, Luke Kwisnek, Charles E. Hoyle, and Sergei I. Nazarenko

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Reversible "Self-Locked" Micelles from a Zwitterion-Containing Triblock Copolymer, Joel D. Flores, Xuewei Xu, Nicolas J. Treat, and Charles L. McCormick

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Clicking Polymer Brushes with Thiol-yne Chemistry: Indoors and Out, Ryan M. Hensarling, Vanessa A. Doughty, Justin W. Chan, and Derek L. Patton

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Amphiphilic Block Copolymers Synthesized via RAFT: Stimulus-Induced Nanoscale Assembly and Cross-Linking In Aqueous Media, Matthew G. Kellum, Adam E. Smith, Xuewei Xu, and Charles L. McCormick

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Temperature-Induced Ordering and Gelation of Star Micelles Based on ABA Triblocks Synthesized Via Aqueous RAFT Polymerization, Stacey Kirkland-York, Keith Gallow, Jacob Ray, Yueh-lin Loo, and Charles L. McCormick

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Oxygen Transport Properties of Thiol-Ene Networks, Luke Kwisnek, Sergei I. Nazarenko, and Charles E. Hoyle

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(Meth)Acrylate Vinyl Ester Hybrid Polymerizations, Tai Yeon Lee, Neil B. Cramer, Charles E. Hoyle, Jeffrey W. Stansbury, and Christopher N. Bowman

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The Thiol-Isocyanate Click Reaction: Facile and Quantitative Access to Omega-End-Functional Poly(N,N-diethylacrylamide) Synthesized by RAFT Radical Polymerization, Haibo Li, Bing Yu, Hironori Matsushima, Charles E. Hoyle, and Andrew B. Lowe

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The Effect of Thiol and Ene Structures on Thiol-ene Networks: Photopolymerization, Physical, Mechanical and Optical Properties, Qin Li, Hui Zhou, and Charles E. Hoyle

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Comparison of Small Molecule and Polymeric Urethanes, Thiourethanes, and Dithiourethanes: Hydrogen Bonding and Thermal, Physical, and Mechanical Properties, Qin Li, Hui Zhou, Douglas A. Wicks, Charles E. Hoyle, David H. Magers, and Harley R. McAlexander

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Cationic Hydroxyethylcellulose: Anionic Surfactant Interactions in the Presence of Salt, Robert Y. Lochhead and Lisa R. Gandolfi

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Recent Advances in Synthesis, Characterization and Rheological Properties of Polyurethanes and POSS/Polyurethane Nanocomposites Dispersions and Films, Samy A. Madbouly and Joshua U. Otaigbe

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Site Transformation of Polyisobutylene Chain Ends into Functional RAFT Agents for Block Copolymer Synthesis, Andrew J.D. Magenau, Nemesio Martinez-Castro, and Robson F. Storey

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Polyisobutylene RAFT CTA by a Click Chemistry Site Transformation Approach: Synthesis of Poly(isobutylene-b-N-isopropylacrylamide), Andrew J. Magenau, Nemesio Martinez-Castro, Daniel A. Savin, and Robson F. Storey

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Primary Halide-Terminated Polyisobutylene: End-Quenching of Quasiliving Carbocationic Polymerization with N-(omega-Haloalkyl)pyrrole, Nemesio Martinez-Castro, David L. Morgan, and Robson F. Storey

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Synthesis and Characterization of Nylon 18 18 and Nylon 18 Adamantane, Lon J. Mathias, Ethem Kaya, Carl Bennett, Allison M. Sikes, and William L. Jarrett

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Molecular Miscibility and Chain Dynamics in POSS/Polystyrene Blends: Control of POSS Preferential Dispersion States, Rahul Misra, Alp H. Alidedeoglu, William L. Jarrett, and Sarah E. Morgan

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POSS-Nylon 6 Nanocomposites: Influence of POSS Structure on Surface and Bulk Properties, Rahul Misra, Bruce X. Fu, Andreas Plagge, and Sarah E. Morgan

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Polymerization Kinetics of rac-Lactide Initiated with Alcohol/Stannous Octoate Using In Situ Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy: An Initiator Study, Scott J. Moravek, Jamie M. Messman, and Robson F. Storey

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Copolymers of rac-Lactide and -Caprolactone: Conventional Copolymerization vs. Macroinitiator Copolymerization, Scott J. Moravek and Robson F. Storey

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End-Quenching of Quasi-Living Isobutylene Polymerizations with Alkoxybenzene Compounds, David L. Morgan and Robson F. Storey

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Sulfonium Ion Adducts from Quasiliving Polyisobutylene and Mono-or Disulfides, David L. Morgan and Robson F. Storey

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Poly(Z-lysine)-Based Organogels: Effect of Interfacial Frustration on Gel Strength, Sandeep S. Naik and Daniel A. Savin

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Model Studies of the Durability of a Titania-Modified Nafion Fuel Cell Membrane, Yatin Patil and Kenneth A. Mauritz

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Durability Enhancement of Nafion (R) Fuel Cell Membranes Via In Situ Sol-Gel-Derived Titanium Dioxide Reinforcement, Yatin P. Patil and Kenneth A. Mauritz

Synthesis of Alkyd/Acrylic Hybrid Latexes For Paper Coating Applications, James W. Rawlins, Richard C. Ferguson, and David E. Delatte

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Synthesis of High Metal-Complexation Linear Elastomers Containing Sym-1,2,4,5-tetrazine Rings, Abdelwahed R. Sayed and Jeffrey S. Wiggins

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Segmented Polythiourethane Elastomers through Sequential Thiol-Ene and Thiol-Isocyanate Reactions, Junghwan Shin, Hironori Matsushima, Justin W. Chan, and Charles E. Hoyle

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Effects of Chemical Modification of Thiol-Ene Networks on Enthalpy Relaxation, Junghwan Shin, Sergei I. Nazarenko, and Charles E. Hoyle

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Physical and Chemical Modifications of Thiol-Ene Networks to Control Activation Energy of Enthalpy Relaxation, Junghwan Shin, Sergei I. Nazarenko, J. Paige Phillips, and Charles E. Hoyle

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Tuning Nanostructure Morphology and Gold Nanoparticle "Locking" of Multi-Responsive Amphiphilic Diblock Copolymers, Adam E. Smith, Xuewei Xu, Thomas U. Abell, Stacey E. Kirkland, Ryan M. Hensarling, and Charles L. McCormick

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Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization in an Inverse Microemulsion System: Homopolymerization, Chain Extension, and Block Copolymerization, Atsushi Sogabe and Charles L. McCormick

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The Synthesis, Characterization and Biocompatibility of Poly(ester urethane)/Polyhedral Oligomeric Silesquioxane Nanocomposites, Wenshou Wang, Yan-lin Guo, and Joshua U. Otaigbe

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Hydrogen Bonding Effects On Aspartate Ester Reactions, C. T. Williams, D. A. Wicks, and William L. Jarrett

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Facile 'One-Pot' Preparation of Reversible, Disulfide-Containing Shell Cross-Linked Micelles from a RAFT-Synthesized, pH-Responsive Triblock Copolymer in Water at Room Temperature, Xuewei Xu, Adam E. Smith, and Charles L. McCormick

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Interface Slippage Study Between Polyamide 12 and Ethylene Butene Copolymer Melt In Capillary Extrusion, Jinhai Yang and James L. White

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Newly UV-Curable Polyurethane Coatings Prepared by Multifunctional Thiol- and Ene-Terminated Polyurethane Aqueous Dispersions Mixtures: Preparation and Characterization, Zhenglong Yang, Douglas A. Wicks, Charles E. Hoyle, Hongting Pu, Junjie Yuan, Decheng Wan, and Yongsheng Liu

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Sequential Thiol-Ene/Thiol-Ene and Thiol-Ene/Thiol-Yne Reactions as a Route to Well-Defined Mono and Bis End-Functionalized Poly(N-isopropylacrylamide), Bing Yu, Justin W. Chan, Charles E. Hoyle, and Andrew B. Lowe

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Synthesis of Di- and Tri-Tertiary Amine Containing Methacrylic Monomers and Their (Co)Polymerization via RAFT, Bing Yu and Andrew B. Lowe

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RAFT Synthesis and Stimulus-induced Self-Assembly in Water of Copolymers Based on the Biocompatible Monomer 2-(Methacryloyloxy)ethyl Phosphorylcholine, Bing Yu, Andrew B. Lowe, and Kazuhiko Ishihara

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Effects of Monomer Functionality and Hydrogen Bonding on the Polymerization Kinetics and Properties of Thiol-Ene Networks, Hui Zhou, Qin Li, Junghwan Shin, and Charles E. Hoyle

Submissions from 2008

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Polyisobutylene-Based Miktoarm Star Polymers Via a Combination of Carbocationic and Atom Transfer Radical Polymerizations, L. Krystin Breland and Robson F. Storey

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Convergent Synthesis of 3-arm Star Polymers from RAFT-Prepared Poly(N,N-diethylacrylamide) via a Thiol-ene Click Reaction, Justin W. Chan, Bing Yu, Charles E. Hoyle, and Andrew B. Lowe

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Kinetics Analysis and Physical Properties of Photocured Silicate-Based Thiol-ene Nanocomposites: The Effects of Vinyl POSS ene On the Polymerization Kinetics and Physical Properties of Thiol-Triallyl Ether Networks, Tolecia S. Clark, Charles E. Hoyle, and Sergei I. Nazarenko

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Poly(lactic Acid) and Chain-Extended Poly(lactic Acid)-Polyurethane Functionalized With Pendent Carboxylic Acid Groups, Tim R. Cooper and Robson F. Storey

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Summer SCIENCE - Enhancing High School Science through Polymers, Sabine Heinhorst, Dana G. Thames, Janet Boyce, and Sarah E. Morgan

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Synthesis and Characterization of Carboxylic Acid-Terminated Polyisobutylenes, Lisa K. Kemp, Andrew B. Donnalley, and Robson F. Storey

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Structural Confirmation of Exo-Olefin-Coupled Polyisobutylene Via Model Compound Synthesis and Characterization, Lisa K. Kemp, Justin E. Poelma, Timothy R. Cooper, and Robson F. Storey

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Thermoreversible Hydrogels From RAFT-Synthesized BAB Triblock Copolymers: Steps Toward Biomimetic Matrices For Tissue Regeneration, Stacey E. Kirkland, Ryan M. Hensarling, Shawn D. McConaughy, William L. Jarrett, and Charles L. McCormick

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Morphology of Poly[(t-butyl acrylate)-b-styrene-b-isobutylene-b-styrene-b-(t-butyl acrylate)] Pentablock Terpolymers and Their Thermal Conversion to the Acrylic Acid Form, James G. Kopchick, Robson F. Storey, William L. Jarrett, and Kenneth A. Mauritz

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Synthesis of Carbonated Vernonia Oil, Noel Man, Sharathkumar K. Mendon, James W. Rawlins, and Shelby F. Thames

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Tailoring the Network Properties of Ca2+ Crosslinked Aloe vera Polysaccharide Hydrogels for in Situ Release of Therapeutic Agents, Shawn D. McConaughy, Stacey E. Kirkland, Nicolas J. Treat, Paul A. Stroud, and Charles L. McCormick

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Structural Characterization and Solution Properties of a Galacturonate Polysaccharide Derived from Aloe Vera Capable of In Situ Gelation, Shawn D. McConaughy, Paul A. Stroud, Brent Boudreaux, Roger D. Hester, and Charles L. McCormick

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RAFT-synthesized diblock and triblock copolymers: thermally-induced supramolecular assembly in aqueous media, Charles L. McCormick, Brent S. Sumerlin, Brad S. Lokitz, and Jonathan E. Stempka

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Synthesis and Characterization of Styrene-Butadiene Rubber-Clay Nanocomposites With Enhanced Mechanical and Gas Barrier Properties, P. Meneghetti, S. Shaikh, Syed Qutubuddin, and Sergei I. Nazarenko

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Substituted Hippurates and Hippurate Analogs As Substrates and Inhibitors of Peptidylglycine Alpha-Hydroxylating Monooxygenase (PHM), David J. Merkler, Alexander S. Asser, Laura E. Baumgart, Natalie Carballo, Sarah E. Carpenter, Geoffrey H. Chew, Casey C. Cosner, Jodi Dusi, Andrew B. Lowe, Edward W. Lowe Jr., Lawrence King III, Robert D. Kendig, Paul C. Kline, Robert Malka, Kathleen A. Merkler, Neil R. McIntyre, Mindy Romero, Benjamin J. Wilcox, and Terence C. Owen

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Reaction Kinetics of Dicyclohexylmethane-4,4'-dilsocyanate With 1-and 2-Butanol: A Model Study for Polyurethane Formation, Scott J. Moravek and Robson F. Storey

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New Poly(ester Amide)s From Alkyl 2-(Carboethoxyhydroxy-Methyl)acrylates, Jean-François Morizur and Lon J. Mathias

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Effect of Relative Humidity On the Young's Modulus of Polyelectrolyte Multilayer Films and Related Nonionic Polymers, Adam J. Nolte, Neil D. Treat, Robert E. Cohen, and Michael F. Rubner

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Aggregation of Synthetic Chrysotile Nanotubes In the Bulk and In Solution Probed By Nitrogen Adsorption and Viscosity Measurements, B. G. Olson, J. J. Decker, Sergei I. Nazarenko, V.E. Yudin, Joshua U. Otaigbe, E.N. Korytkova, and V.V. Gusarov

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New Well-Defined Polymeric Betaines: First Report Detailing the Synthesis and ROMP of Salt-Responsive Sulfopropylbetaine- and Carboxyethylbetaine-Exo-7-Oxanorbornene Monomers, David A. Rankin and Andrew B. Lowe

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Promotion of the Gamma-Phase of Polyamide 6 In its Nanocomposite With Phosphate Glass, A. Rawal, X.-W. Fang, K. Urman, D. Iverson, Joshua U. Otaigbe, and K. Schmidt-Rohr

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Synthesis and Characterization of Soyamide Ferulate, James W. Rawlins, Monoj Pramanik, and Sharathkumar K. Mendon

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1,3-Dipolar Cycloaddition Polymerization Reactions of Novel Macromolecules Containing Sym-Tetrazine Rings, Abdelwahed R. Sayed and Jeffrey S. Wiggins

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Enthalpy Relaxation of Photopolymerized Thiol-ene Networks: Structural Effects, Junghwan Shin, Sergei I. Nazarenko, and Charles E. Hoyle

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Synthesis and Characterization of Novel Biodegradable and Biocompatible Poly(ester-urethane) Thin Films Prepared by Homogeneous Solution Polymerization, Wenshou Wang, Yanlin Guo, and Joshua U. Otaigbe

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Kinetic Evaluation of Tin-POMS Catalyst for Urethane Reactions, Wenshou Wang and Jeffrey S. Wiggins

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Polyhedral Oligomeric Silsesquioxane Trisilanols As Dispersants For Titanium Oxide Nanopowder, Paul A. Wheeler, Rahul Misra, Robert D. Cook, and Sarah E. Morgan

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Aqueous RAFT Synthesis of pH-Responsive Triblock Copolymer mPEO-PAPMA-PDPAEMA and Formation of Shell Cross-Linked Micelles, Xuewei Xu, Adam E. Smith, Stacey E. Kirkland, and Charles L. McCormick

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Nanoencapsulation of Blocked Isocyanates Through Aqueous Emulsion Polymerization, H. Yang, S. K. Mendon, and James W. Rawlins

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Advances in the Synthesis of Amphiphilic Block Copolymers via RAFT Polymerization: Stimuli-Responsive Drug and Gene Delivery, Adam W. York, Stacey E. Kirkland, and Charles L. McCormick

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Effects of Three Crosslinkers On Colored pH-Responsive Core-Shell Latexes, Bing Yuan, Jeremy States, Chris Sahagun, and Douglas Wicks

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Effects of Nanofiller Morphology and Aspect Ratio On the Rheo-Mechanical Properties of Polyimide Nanocomposites, V.E. Yudin, Joshua U. Otaigbe, V.M. Svetlichnyi, E.N. Korytnova, O.V. Almjasheva, and V.V. Gusarov

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Photopolymerization Kinetics of Tributylmethylammonium-Based (Meth)acrylate Ionic Liquids and the Effect of Water, Hui Zhou, Zulma Jiménez, John A. Pojman, Mark S. Paley, and Charles E. Hoyle

Submissions from 2007

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Copolymerization of Sec-Butenyl Acetate With Styrene Via Emulsion Polymerization, Alp H. Alidedeoglu, Sandipan Dutta, Rahul Misra, James W. Rawlins, and Sarah E. Morgan

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Incorporation of Drying Oils Into Emulsion Polymers For Use in Low-VOC Architectural Coatings, Gregory Booth, David E. Delatte, and Shelby F. Thames

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Epoxy Phosphonate Crosslinkers for Providing Flame Resistance to Cotton Textiles, SeChin Chang, Navzer (Nozar) D. Sachinvala, Paul Sawhney, D. V. Parikh, William Jarrett, and Casey Grimm

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First Solvent-Free Synthesis of Poly(N-methylolacrylamide) Via Frontal Free-Radical Polymerization, Li Chen, Ting Hu, Huan Yu, Su Chen, and John A. Pojman

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Thermal Polymerization of Thiol-ene Network-Forming Systems, Wayne D. Cook, Fei Chen, Derek W. Pattison, Peyton Hopson, and Mathieu Beaujon

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Characterization of Poly(ethyleneoxyethylene Terephthalate-co-adipate) Using NMR Spectroscopy, Tim R. Cooper and Robson F. Storey

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Electrolyte- and pH-Responsive Polyampholytes With Potential As Viscosity-Control Agents In Enhanced Petroleum Recovery, Ryan G. Ezell and Charles L. McCormick

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Broadband Dielectric Spectroscopic Characterization of the Hydrolytic Degradation of Carboxylic Acid-Terminated Poly(D,L-lactide) Materials, Mohammad K. Hassan, Jeffrey S. Wiggins, Robson F. Storey, and Kenneth A. Mauritz

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Photopolymerization Kinetics of Ionic Liquid Monomers Derived From the Neutralization Reaction Between Trialkylamines and Acid-Containing (Meth)acrylates, Zulma Jiménez, Christopher Bounds, Charles E. Hoyle, Andrew B. Lowe, Hui Zhou, and John A. Pojman

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Poly[acrylic acid-b-styrene-b-i sobutylene-b-styrene-b-acrylic acid] Pentablock Terpolymers: 1. Morphological Characterization, James G. Kopchick, Robson F. Storey, Frederick L. Beyer, and Kenneth A. Mauritz

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The Effect of Concentration In Electrochemical Oxidation of Thiocyanate On Platinum Electrode, P. Krishnan

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Preparation and Characterization of Proton-Conducting Sulfonated Poly(ether ether ketone)/Phosphatoantimonic Acid Composite Membranes, Palanichamy Krishnan, Jin-Soo Park, and Chang-Soo Kim

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Effect of Uniaxial Drawing of Soy Protein Isolate Biopolymer Film On Structure and Mechanical Properties, Takashi Kurose, Kevin Urman, Joshua U. Otaigbe, and Robert Y. Lochhead

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Compatibilized Polyimide (R-BAPS)/BAPS-Modified Clay Nanocomposites With Improved Dispersion and Properties, Takashi Kurose, Vladimir E. Yudin, Joshua U. Otaigbe, and V.M. Svetlichnyi

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Thiourethane-Based Thiol-ene High T-g Networks: Preparation, Thermal, Mechanical, and Physical Properties, Qin Li, Hui Zhou, Douglas A. Wicks, and Charles E. Hoyle

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Stimuli-Responsive Block Copolymers by RAFT and Their Micellization Behavior, Yuting Li, Brad Lokitz, and Charles L. McCormick

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In Situ Formation of Gold-"Decorated" Vesicles From a RAFT-Synthesized, Thermally Responsive Block Copolymer, Yuting Li, Adam E. Smith, Brad S. Lokitz, and Charles L. McCormick

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Investigation of the Effects of Polymer Microstructure On the Rheologies of Polyelectrolyte Gels: The Importance of Chain Rigidity, Branching, Hydrophobic Modification and Polymer-Particle Interaction, Robert Y. Lochhead

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The Use of Polymers in Emulsions, Robert Y. Lochhead

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Aqueous RAFT Synthesis of Micelle-Forming Amphiphilic Block Copolymers Containing N-Acryloylvaline. Dual Mode, Temperature/pH responsiveness, and "Locking" of Micelle Structure Through Interpolyelectrolyte complexation, Brad S. Lokitz, Adam W. York, Jonathan E. Stempka, Neil D. Treat, Yuting Li, William L. Jarrett, and Charles L. McCormick

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RAFT Synthesis and Solution Properties of pH-Responsive Styrenic-Based AB Diblock Copolymers of 4-Vinylbenzyltrimethylphosphonium Chloride with N,N-Dimethylbenzylvinylamine, Andrew B. Lowe, Ran Wang, Venkataswarup Tiriveedhi, Peter Butko, and Charles L. McCormick

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Crystallization Kinetics of PHB/PVAc Blends Using Time Resolved Dielectric Spectroscopy, Samy A. Madbouly, Ashraf A. Mansour, and Nahed Y. Abdou